I can’t recall any pyRevit windows out of the box being modeless. What I’m wortking on currently has a modeless window but with a slightly different purpose, however you might use it as a starting point:
Another one:
As you can see, the included WPFWIndow is somewhat prepared for being shown in modeless form, but needs extra caution and efforts, if you want to interact with the Revit API in that context.